A Wright radial aircraft engine was developed using turbocompounding. It was installed in some very big planes. There is a discussion on Wikipedia.
http://en.wikipedia.org/wiki/Wright_R-3350
Turbocompounding increases efficiency at full load, good for planes, but lousy for cars. Automobile engines rarely operate at full load. Part load efficiency in cars could suck, because a turbine would have to be sized for full exhaust, but mostly operate at a fraction of full load.
It might be cost effective to drive auxiliary systems like the alternator and water pumps using a small turbine downstram of the catalyst. It would have to be equipped with a byapss (wastegate) to allow full power without restriction.
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