Yes, when capacitors blow, they can do so rather spectacularly...I was using an old tube type Sansui stereo my brother brought back after a tour in 'Nam. One day, I heard a loud 'pop' from the set...there was one of the filter caps, blown apart, foil expanded out everywhere!
It was a quick fix, of course, solder in a new cap and the set was good as new. But magnify that by the amount of current required in a car, and you might get an idea of what could happen if a cap failed.
A charged capacitor can hold a charge for quite a while...when working on old tube type radios and TV sets, the wise person always, after removing power, shorts all electrolytic capacitors. Most sets have a way of bleeding off the charge, but since the caps can hold a potentially fatal charge, one should never trust such bleeder devices.
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