I don't think changing your injectors will affect FE (fuel economy), just maximum power. Your car's computer monitors air/fuel ratio and adjusts injector duty cycle to make it right.
Your MPG figures seem low if you're shifting at a reasonable 2000RPM, which is probably where the EPA tester shifts too. Even with moderate modifications I'd expect better than that.
I bet that Z06 will be a BEAST with the new motor!
So, some strategies for what you can do...shifting lower may help. I shift my economy car at 1200-1500 and on average I keep up with traffic (sometimes I have to back off, sometimes I have to let it run up a little higher); your torque beasts ought to be plenty fast shifting like that too, though turbochargers change the game a bit. Except when a turbo is involved, it's usually more efficient to step on the gas more at lower RPM. You'll sacrifice a little bit of engine/exhaust noise that you probably enjoy with those cars, though.
You may be able to increase your tire pressure. However, those cars tend to come with some pretty large tires, and since they're hardcore performance vehicles they may come specified with high pressure for good handling instead of the usual lowest safe pressure for comfort. Never exceed the maximum stamped on the tire sidewall, never go below the car's recommended pressure. Experiment in that range and see if anything works.
Aerodynamic modifications would be a crying shame with those cars.
A warm air intake would slightly reduce your top-end power, which I imagine is not an acceptable compromise for someone who's putting a ballsier-than-stock motor in a Z06.
I'd guess that you have custom tunes on the cars? Can you get them adjusted? The only adjustment I can think of would be aggressive DFCO (Deceleration Fuel Cut Off) that kicks in immediately and stays on until almost idle.
So, we're back to driving style. I bet those cars handle really well. Within the limits of legality, etiquette, safety, and visibility, go ahead and enjoy that handling; don't brake for turns.
Red light coming up? It might be fun to blast up to the red light in your cars and stop short, but it's a waste and doesn't get you to your desination any faster. The most efficient way to do it is, as soon as you see the red light, guess the speed you can coast to coast right through as it turns green and adjust to that speed immediately.
How do you feel about coasting in neutral with the engine on?