It is a very good and a very sound idea (and not only because I imagined it myself some time ago, only to find others well ahead of me).
As others point out there are fundamental challenges including heat, rpm, incompatible torque/rpm ranges and so on. None of these are insurmountable however and I believe the trade space will result in a worthwhile difference in fuel economy mainly by allowing a smaller engine to propel a given car without loss in power delivered to the wheels.
The KEY thing with this idea is to look at the energy stealers on a car: steering and brake pumps, water pump, oil pump, a/c.
All of these can be electrically powered. In the case of the water pump and oil pump it may be a good idea to leave as is but the brakes and steering waste energy all of the time when they are not even doing anything useful.
It is only in getting rid of these 'drags' (as well as the alternator on the belt) that the turbo alt will payoff.
Alternators running up to 30,000 rpm have been designed. Such is likely possible for an automobile alternator. Getting the turbo output down below 30,000 rpm is needed (and will increase torque which is a good thing). The turbo can be made larger in diameter (lower gas volume rate over the circumference) too (which also increases torque).
Keep at it. This is a good idea. Just wish I was more of a tinkerer.
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