It's great that you're getting good results!
I don't think increased octane will increase your fuel economy. However, you can certainly try it and see. Just be sure to do long-term A-B-A testing before you declare it a success or failure. It's easy enough to do in this case.
I'd be interested to find out how you do on E85 but I suspect that it will be as BEEF says, you will lose fuel economy with it. Of course, if you lose 20% of your MPG but the E85 costs you 50% less then you come out ahead on cost, and if you're in it for environmentalism then it's probably a win too.