I don't believe that any amount of aerodynamic improvement will make that motor good for 100MPG in mixed driving. It may get close to that on the highway, but it's too big for all of the idling city driving requires. An engine half that size setup as a series hybrid in a more aerodynamic shell could likely do it however.
The key, IMO, is to never allow the motor to idle. It should either be generating useable power for motion or charging batteries, otherwise it should shutoff when no power is needed. Any setup that fails to do that simply isn't going to get there without serious compromises in performance or efficiency.
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